羟甲基酚丙烯酸酯的合成及粘接性能  

Synthesis and Adhesive Performances of Phenol Hydroxymethyl Acrylate

作　　者：丁斌[1] 关昶[1] 金朝辉[1] 韩运华[1] 

机构地区：[1]吉林化工学院化工系,吉林吉林132022

出　　处：《化学与粘合》2003年第4期159-161,164,共4页Chemistry and Adhesion

基　　金：吉林省教育厅基金资助项目 [(吉教科验 )2 0 0 0 3 7号 ]

摘　　要：以甲醛、苯酚和丙烯酸为原料,经缩合、酯化反应合成了多羟甲基酚丙烯酸酯。考察了胶样的破坏强度、耐热性、稳定性以及N-苯基马来酰亚胺对胶样耐热性的影响。结果表明,以多羟甲基酚丙烯酸酯为活性单体,可制一种新型厌氧性耐热胶粘剂。此外,N-苯基马来酰亚胺可明显改善胶样的耐热性能。With formaldehyde, phenol and acrylic acid as raw materials, phenol- trihydroxymethyl triacrylate was synthesized through condensation and esterification. Then, a new anaerobic heat-resistant adhesive was prepared with the above acrylate. The effect of different synthetic conditions on the performances of the adhesive was investigated by test of the bonding strength, heat-resistance and the stability. The effect of N-phenylmaleimide on the heat-resistance of the adhesive was investigated by the decomposition temperature test of the adhesives. Results showed that the decomposition temperature of the adhesives was elevated as N-phenylmaleimide was incorporated in the adhesives.

关 键 词：羟甲基酚丙烯酸酯 合成 粘接性能 甲醛 苯酚 丙烯酸 厌氧性耐热胶粘剂 N-苯基马来酰亚胺 耐热性能 

分 类 号：TQ433.436[化学工程]