Synthesis and Characterization of a Novel Perfluorinated Ionomer Polymer Containing Sulfonimide Functionality  

Synthesis and Characterization of a Novel Perfluorinated lonomer Polymer Containing Sulfonimide Functionality

作　　者：朱士正 章云祥 金桂芳 DesMarteau Darryl D 

机构地区：[1]Shanghai Institute of Organic Chemistry,Chinese Academy of Sciences, Shanghai 200032, China [2]Department of Chemistry, H. L. Hunter Chemistry Laboratory Clemson University, Clemson, SC 29634-1905

出　　处：《Chinese Journal of Chemistry》2003年第7期921-925,共5页中国化学（英文版）

基　　金：Project supported by the National Natural Science Foundation of China(Nos.20032010,20072049).

摘　　要：The novel perfluorinated vinyl ether containing sulfonimide functionality CF2 = CFORfSO2NHSO2CF3 was synthesized by multiple reaction steps. It could be copolymerized with tetraflu-oroethylene by radox initiator to give a novel perfluorinated ionomer polymer. Its physical and chemical properties were studied.The novel perfluorinated vinyl ether containing sulfonimide functionality CF2 = CFORfSO2NHSO2CF3 was synthesized by multiple reaction steps. It could be copolymerized with tetraflu-oroethylene by radox initiator to give a novel perfluorinated ionomer polymer. Its physical and chemical properties were studied.

关 键 词：perfluorinated vinyl ether sulfonimide copolymer-ization IONOMER RESIN 

分 类 号：O631[理学—高分子化学]