Synthesis of Coronene Using Microwave Irradiation  

作　　者：Bing YANG Ying LI Ming Gui XIE 

机构地区：[1]Faculty of Chemistry,Sichuan University,Chengdu 610064

出　　处：《Chinese Chemical Letters》2003年第8期783-785,共3页中国化学快报(英文版)

摘　　要：Using microwave irradiation, perylene was obtained from 3,4,9,10-perylenetetracar- boxylic dianhydride with copper powder in boiling quinoline. With the same method, 1,12- benzoperylene was synthesized from 1, 12-benzoperylene-1, 2-dicarboxylic anhydride, and coronene was prepared from coronene-1, 2- dicarboxylic anhydride with good yield. Through Dields-Alder reaction, 1, 12-benzoperylene-1, 2-dicarboxylic anhydride and coronene-1,2- dicarboxylic anhydride were also prepared using microwave irradiation.Using microwave irradiation, perylene was obtained from 3,4,9,10-perylenetetracar- boxylic dianhydride with copper powder in boiling quinoline. With the same method, 1,12- benzoperylene was synthesized from 1, 12-benzoperylene-1, 2-dicarboxylic anhydride, and coronene was prepared from coronene-1, 2- dicarboxylic anhydride with good yield. Through Dields-Alder reaction, 1, 12-benzoperylene-1, 2-dicarboxylic anhydride and coronene-1,2- dicarboxylic anhydride were also prepared using microwave irradiation.

关 键 词：CORONENE PERYLENE MICROWAVE synthesis. 

分 类 号：O621.392[理学—有机化学]