N-(4-羟基苯基亚甲基)-1-萘胺的室温固相合成、表征及晶体结构  

Solid Phase Synthesis, Characterization and Crystal Structure of N-(4-Hydroxyphenylmethylene)-1-Naphthylamine

作　　者：李人宇[1] 卑凤利[1] 杨绪杰[1] 许兴友[1] 陆路德[1] 汪信[1] 

机构地区：[1]南京理工大学材料化学实验室

出　　处：《应用化学》2003年第9期911-913,共3页Chinese Journal of Applied Chemistry

基　　金：江苏省自然科学基金资助项目 (BK2 0 0 2 10 0 )

摘　　要：N-(4-Hydroxyphenylmethylene)-1-naphthylamine was synthesized by the solid phase reaction of 1-naphthylamine and 4-hydroxybenzaldehyde at room temperature. The reaction was completed in 15 min in yield of 95%. The product was characterized by elemental analysis, IR, X-ray powder diffractometry and 1H NMR. The crystal as determined by X-ray single crystal diffractometry belongs to monoclinic system with space group P2 1/c, a=1.004 9(2), b=1.047 3(2), c=1.200 2(2) nm, β=92.60(3)°, V= 1.261 8(4) nm 3, D c=1.302 g/cm 3, Z=4, F(000)=528, μ=0.081 mm -1, R=0.0375, wR=0.106 2, S=1.024.N-(4-Hydroxyphenylmethylene)-1-naphthylamine was synthesized by the solid phase reaction of 1-naphthylamine and 4-hydroxybenzaldehyde at room temperature. The reaction was completed in 15 min in yield of 95%. The product was characterized by elemental analysis, IR, X-ray powder diffractometry and 1H NMR. The crystal as determined by X-ray single crystal diffractometry belongs to monoclinic system with space group P2 1/c, a=1.004 9(2), b=1.047 3(2), c=1.200 2(2) nm, β=92.60(3)°, V= 1.261 8(4) nm 3, D c=1.302 g/cm 3, Z=4, F(000)=528, μ=0.081 mm -1, R=0.0375, wR=0.106 2, S=1.024.

关 键 词：N-(羟基苯基亚甲基)萘胺 schiff碱 固相反应 晶体结构 

分 类 号：O622[理学—有机化学]