新型一维[Co(phen)(μ_3-md)]_n的水热合成与结构  

Hydrothermal Synthesis and Structure of A Novel [Co(phen)(μ_3-md)]_n

作　　者：李传碧[1] 张丽娟[1] 孙英华[1] 李泳[1] 王铁钢[1] 徐吉庆[1] 

机构地区：[1]吉林大学化学学院,无机合成与制备化学国家重点实验室,长春130023

出　　处：《高等学校化学学报》2003年第8期1366-1367,共2页Chemical Journal of Chinese Universities

基　　金：国家自然科学基金 (批准号 :2 97330 90 );高等学校博士学科点专项科研基金 (批准号 :19990 18310 )资助

摘　　要：A novel 1-D compound, [Co(phen)(μ 3-md)] n, was hydrothermally synthesized and characterized by single crystal X-ray diffraction analysis, elemental analysis and IR spectra. This compound was crystallized in monoclinic system, space group P2/C with a=0.832 9(18) nm, b=1.041 35(11) nm, c=1.834 8(5) nm, β=100.436(18)°, D c=1.706 mg/cm 3, R 1= 0.037 9, wR 2=0.086 6. The 1-D double-chain structure of the title compound is formed by benzene-1,3-dicarboxylate connected with three Co atoms.A novel 1-D compound, [Co(phen)(μ 3-md)] n, was hydrothermally synthesized and characterized by single crystal X-ray diffraction analysis, elemental analysis and IR spectra. This compound was crystallized in monoclinic system, space group P2/C with a=0.832 9(18) nm, b=1.041 35(11) nm, c=1.834 8(5) nm, β=100.436(18)°, D c=1.706 mg/cm 3, R 1= 0.037 9, wR 2=0.086 6. The 1-D double-chain structure of the title compound is formed by benzene-1,3-dicarboxylate connected with three Co atoms.

关 键 词：[Co(phen)(μ3-md)]n 水热合成 晶体结构 一维双链结构 间苯二甲酸 聚合物 

分 类 号：O614.812[理学—无机化学] O634[理学—化学]