苯乙炔封端的可交联含氟聚芳醚的合成及性能  

Synthesis and Properties of Crosslinkable Fluorinated Poly(aryl ethers) Terminated with Phenylethynyl Moieties

作　　者：呼微[1] 刘佰军[1] 王冬[1] 马小野[1] 饶先花[1] 李婷[1] 姜振华[1] 吴忠文[1] 

机构地区：[1]吉林大学化学学院,长春130023

出　　处：《高等学校化学学报》2003年第8期1522-1524,共3页Chemical Journal of Chinese Universities

基　　金：国家自然科学基金 (批准号 :5 0 2 0 30 0 4)资助

摘　　要：The crosslinkable trifluoromethylated poly(aryl ethers) terminated with phenylethynyl moieties(11F-PAE-PEP)s were prepared in two step syntheses. The structure of 11F-PAE-PEP was confirmed by FTIR and 1H NMR. The crosslinking behavior was studied by DSC. There is a remarkable increase of T g after crosslinking of the poly(aryl ethers). The T g values of crosslinked polymers were 437 and 446 K, respectively. The crosslinked polymers could not be soluble in common organic solvents, such as N,N-dimethylformamide, N,N-dimethylacetamide, N-methyl-2-pyrrolidinone, chloroform, and tetrahydrofuran. The temperatures at a 5% mass loss of the crosslinked polymers in air were above 789 K. They showed a good optical property, too. This kind of polymers will be the promising materials used as the microelectronics and optical waveguide devices.The crosslinkable trifluoromethylated poly(aryl ethers) terminated with phenylethynyl moieties(11F-PAE-PEP)s were prepared in two step syntheses. The structure of 11F-PAE-PEP was confirmed by FTIR and 1H NMR. The crosslinking behavior was studied by DSC. There is a remarkable increase of T g after crosslinking of the poly(aryl ethers). The T g values of crosslinked polymers were 437 and 446 K, respectively. The crosslinked polymers could not be soluble in common organic solvents, such as N,N-dimethylformamide, N,N-dimethylacetamide, N-methyl-2-pyrrolidinone, chloroform, and tetrahydrofuran. The temperatures at a 5% mass loss of the crosslinked polymers in air were above 789 K. They showed a good optical property, too. This kind of polymers will be the promising materials used as the microelectronics and optical waveguide devices.

关 键 词：苯乙炔端基 交联 含氟聚芳醚 合成 性能 含氟聚合物 光电集成器件 

分 类 号：O632.32[理学—高分子化学] TN15[理学—化学]