3,3′,5,5′-四甲基-4,4′-联苯二醌的合成  

Synthesis of 3,3′,5,5′-Tetramethyl-4,4′-diphenoquinone

作　　者：李胜方[1] 付继芳[1] 袁庆荣[1] 王洛礼[1] 

机构地区：[1]湖北省化学研究所,武汉430074

出　　处：《精细石油化工进展》2003年第7期35-37,共3页Advances in Fine Petrochemicals

摘　　要：以 2 ,6-二甲基苯酚、氧气为原料 ,氨水与乙酸铜为催化剂 ,合成得到了 3 ,3′,5 ,5′ -四甲基 -4 ,4′-联苯二醌 ,得到反应的最佳条件为 :2 ,6-二甲基苯酚的浓度为 0 .1g/mL ,氨水与乙酸铜的摩尔比为 0 .43 ,温度为 75℃ ,反应时间为 6h ,产率达到 60 %。3,3′,5,5′-tetramethyl-4,4′-diphenoquinone was synthesized.In the reaction,2,6-dimethylphenol was used as raw material, amine and copper acetate were used as catalyst.The reaction conditions were examined as follows: the concentration of 2,6-dimethylphenol 0.1 g/mL , the molar ratio of amine to copper acetate 0.41∶1,the reaction temperature 75 ℃ , the reaction time 6 hours with the overall yield of 60%.

关 键 词：3 3’ 5 5’-四甲基-4 4’-联苯二醌 合成 2 6-二甲基苯酚 氧气 原料 

分 类 号：O625[理学—有机化学]