环氧基倍半硅氧烷丙烯酸树酯的合成研究  

Study on the synthesis of epoxy silsesquioxane acrylate resin

作　　者：任亚国 马家举[1] 赵容[1] 

机构地区：[1]安徽理工大学,安徽淮南232001

出　　处：《热固性树脂》2015年第3期9-12,共4页Thermosetting Resin

摘　　要：以β-(3,4-环氧环己基乙基)三甲氧基硅烷水解缩合制备了环氧基倍半硅氧烷(EP-POSS),产物再与丙烯酸通过酯化反应得倍半硅氧烷丙烯酸树脂(EA-POSS),并采用FT-IR和1H-NMR对产物结构进行表征。研究了催化剂种类和用量以及反应温度对EP-POSS酯化反应的影响,结果表明,以四丁基溴化铵(TBAB)为催化剂,添加质量分数0.6%,反应温度110℃,反应时间90 min条件下,转化率可达94.56%。Theepoxysilsesquioxane(EP-POSS)was prepared by hydrolysis condensation of β-(3,4-Epoxycyclohexylethyl)trimethoxysilane.Then the epoxy silsesquioxane acrylate resin(EA-POSS)was synthesized by the esterification of EP-POSS and acrylic acid. The products were characterized by FT-IR and1H-NMR. The effects of species and amount of catalyst and reaction temperature on the esterification of EP-POSS were investigated. The result indicated the yield could reach 94.56% as the conditions as followed:tetrabutyl ammonium bromide(TBAB)as catalyst,catalyst amount 0.6%,reaction temperature 110 ℃ and reaction time 90 mins.

关 键 词：环氧基倍半硅氧烷 丙烯酸树脂 酯化反应 催化剂 反应温度 

分 类 号：TQ314.24[化学工程—高聚物工业]