杯芳冠醚与碱金属离子配合热力学分析  

Thermodynamics Analysis for Complexes of Calixcrown With Alkali Metal Ions

作　　者：高建勋[1] 王建晨[1] 宋崇立[1] 

机构地区：[1]清华大学核能技术设计研究院,北京100084

出　　处：《原子能科学技术》2003年第4期313-319,共7页Atomic Energy Science and Technology

基　　金：国家"95"科技攻关项目(96 A18 01)

摘　　要：概要介绍了杯芳冠醚与碱金属离子配合的热力学研究方面的最新进展,较为系统地分析了选择性与热力学参数之间的相关性,得出了一般规律。Recent progresses in thermodynamic study on the coordination of calixcrowns to alkali metal ions were introduced. The relationship between the selectivity of calixcrowns towards alkali metal ions and thermodynamic parameters was systemically analyzed, and some general rules were drawn.

关 键 词：杯芳冠醚 碱金属离子 热力学参数 选择性 相关性 配台 高放废液 萃取剂 废液处理 

分 类 号：TL941.1[核科学技术—辐射防护及环境保护]