N-(α-甲基-丁酯基)马来酰亚胺微乳液聚合的动力学研究  

Microwave radiation polymerization and heat polymerization of N-(butyl α-methyl-acetate) maleimide microemulsion

作　　者：黄梅芳[1] 刘朋生[1] 

机构地区：[1]湘潭大学化学学院,湖南湘潭411105

出　　处：《弹性体》2003年第4期26-27,共2页China Elastomerics

基　　金：湖南省自然科学基金项目(01JJY3011)

摘　　要：以十二烷基硫酸钠为乳化剂,过硫酸钾为引发剂,使N (α 甲基 丁酯基)马来酰亚胺的微乳液聚合,并对其动力学进行了研究。考察了引发剂浓度、乳化剂浓度、单体浓度对聚合的影响,得到三者的曲线斜率分别为0.5,1.17,1.22。Microemulsion of SDS/monomer/H2O is firstly prepared.On this basis,the microemulsion of N(butyl αmethylacetate) maleimide was polymerized with potassium persulfate as an initiator.The influence of reaction temperate on yield had been studied.The dependency of polymerization rate on concentration of KPS,monomer and SDS were 0.5,1.22,1.17.

关 键 词：N-(α-甲基-丁酯基)马来酰亚胺 微乳液聚合 动力学 乳化剂 过硫酸钾 引发剂 

分 类 号：TQ326.9[化学工程—合成树脂塑料工业] TQ316.334