纳米碳酸钙粒子用作润滑油添加剂的研究  

Study on the Application of CaCO_3 Nanoparticles as Additives in Lubricating Oils

作　　者：顾卓明[1] 顾彩香[1] 王仁兵[1] 金国平[1] 

机构地区：[1]上海海运学院商船学院,上海200135

出　　处：《上海海运学院学报》2003年第3期227-231,共5页Journal of Shanghai Maritime University

基　　金：上海市科委纳米专项资金资助(0211nm100);上海市教委重点项目基金(02IZ22)

摘　　要：采用X射线衍射仪和透射电镜检验了纳米碳酸钙粒子的粒径和内部结构,根据亲水亲油平衡值(HLB),选择合适的表面活性剂将其加入到含有纳米碳酸钙粒子的润滑油中进行表面改性。通过测试最大无卡咬负荷、观察磨斑表面形貌和测定磨斑直径以及测试摩擦系数,对纳米碳酸钙粒子的极压性能和抗磨减摩性能进行了分析和研究;通过XPS测试对纳米碳酸钙润滑油添加剂进行了摩擦化学的分析和研究,对纳米碳酸钙粒子的抗磨减摩机理进行了系统的分析。研究结果表明,含有纳米碳酸钙粒子的润滑油具有良好的摩擦学性能。This paper has insepectd the size and the structure of the calcium carbonate (CaCO3) particles by adopting X-ray diffraction and Transmission Electron Microscope (TEM). According to Hydrophile and Lipophile Balance (HLB), the suitable surface-active agents have been selected and put into lubricating oil with nanometer CaCO3 particles. By testing some parameters, such as the maximum non-seizure load, the shape and diameter of wear scar, the friction factor, the nanometer CaCO3 particles' properties of extreme pressure, anti-wear and friction reduction have been tested and analyzed. The properties of the nanometer CaCO3 particles' tribology chemistry have been analyzed through X-ray Photoelectron Spectrum test. Also the nanometer CaCO3 particles' mechanism of anti-wear and friction reduction has been studied systematically. The research results show that, the lubricating oil with nanometer CaCO3 particles has good triblogical properties.

关 键 词：纳米碳酸钙粒子 润滑油添加剂 表面活性剂 润滑油 抗摩减摩性能 

分 类 号：TE624.82[石油与天然气工程—油气加工工程] TE626.3