含铜氮配键腰果酚醛缩聚物的特性及表征  

CHARACTERIZATION OF CARDANOL-ALDEHYDE CONDENSATION POLYMER CONTAINING COPPER-NITROGEN COORDINATED BOND

作　　者：陈玉[1] 林金火[1] 

机构地区：[1]福建师范大学高分子研究所,福建福州350007

出　　处：《林产化学与工业》2003年第3期61-64,共4页Chemistry and Industry of Forest Products

基　　金：国家自然科学基金资助项目(A20174005);福建省自然科学基金资助项目(E0110022)

摘　　要：　腰果酚醛树脂中含有较活泼的酚羟基,略显酸性,易受碱的腐蚀。先由共缩聚法得到以苯胺改性的腰果酚醛缩聚物,再使之与CuCl2反应,合成含铜 氮配键腰果酚醛缩聚物。用IR、动态粘弹谱(DMTA)、TG和其他手段对产物的结构和理化性能进行表征。结果表明,金属铜离子与苯胺分子中氮原子形成配位键,增大了涂膜内部的交联度,使分子链间形成更大的网状结构。因此,含铜 氮配键腰果酚醛涂膜的物理机械性能、热稳定性、耐化学介质尤其是耐碱性能得到很大的改善。Cardanolaldehyde condensation resin(CF) is susceptible to corrosion by alkali because of its slight acidity of phenolic hydroxyls.CF was modified by aniline,followed by reaction with CuCl2.The final product of the cocondensation polymer containing coppernitrogen coordinated bond(CFNCu) has been synthesized and characterized by IR,dynamic mechanical thermogram analysis(DMTA) and other measures.Results show that coppernitrogen coordinated bond increases the crosslinking of coating film,leading to the remarkable improvements of physicomechanical properties,thermostability and resistance against chemical media,especially alkali.

关 键 词：铜-氮配键 腰果酚醛缩聚物 特性 表征 腰果壳液 涂料 

分 类 号：TQ633[化学工程—精细化工]