Synthesis and Characterization of a 42-Membered Macrocyclic Compound C_(40)H_(46)N_6O_4 with [2+2] Condensation  

作　　者：MAZhen LIUShi-Xiong 

机构地区：[1]CentralLaboratory,FuzhouUniversity,Fuzhou350002,China [2]StateKeyLaboratoryofStructuralChemistry,FujianInstituteofResearchontheStructureofMatter,TheChineseAcademyofSciences,Fuzhou350002,China

出　　处：《Chinese Journal of Structural Chemistry》2003年第5期553-557,共5页结构化学（英文）

基　　金：The project was financially supported from the National Natural Science Foundation of China (No. 20171012);;;;;;; and the Natural Science Foundation of Fujian province (No.E0110010)

摘　　要：The title compound 1,4,23,26,29,48-hexaaza-6,9:16,19:31,34:41,44-tetrabenzo-12, 15,37,40-tetraoxa-cyclodotetracontane-4,5,18,19,25,26,39,40-octaene 1 (C40H46N6O4) was synthe- sized by [2+2] condensation of diethylenetriamine with 4,4?diformyl-diphenoxyethane (dialdehyde) in a mixed solvent of ethanol and tetrahydrofuran. The crystal data are: Mr = 674.83, triclinic, P, a = 5.8249(1), b = 9.4114(8), c = 17.649(2) ? a = 79.310(7), b = 85.397(4), g = 78.970(8), V = 932.1(1) ?, Z = 1, Dc = 1.202 g/cm3, F(000) = 360, m(MoKa) = 0.079 mm-1, R = 0.0486 and wR = 0.1439. The title molecule has a crystallographic center symmetry. The distance between the two secondary amine nitrogen atoms is 18.890(3) ?The title compound 1,4,23,26,29,48-hexaaza-6,9:16,19:31,34:41,44-tetrabenzo-12, 15,37,40-tetraoxa-cyclodotetracontane-4,5,18,19,25,26,39,40-octaene 1 (C40H46N6O4) was synthe- sized by [2+2] condensation of diethylenetriamine with 4,4?diformyl-diphenoxyethane (dialdehyde) in a mixed solvent of ethanol and tetrahydrofuran. The crystal data are: Mr = 674.83, triclinic, P, a = 5.8249(1), b = 9.4114(8), c = 17.649(2) ? a = 79.310(7), b = 85.397(4), g = 78.970(8), V = 932.1(1) ?, Z = 1, Dc = 1.202 g/cm3, F(000) = 360, m(MoKa) = 0.079 mm-1, R = 0.0486 and wR = 0.1439. The title molecule has a crystallographic center symmetry. The distance between the two secondary amine nitrogen atoms is 18.890(3) ?

关 键 词：crystal structure macrocyclic compound CONDENSATION 

分 类 号：O624[理学—有机化学] O641[理学—化学]