纳米C_(60)/C_(70)-丙烯酸(酯)共聚物的合成及性能  

STUDY ON SYNTHESIS AND PROPERTIES OF POLYMER OF NANOMETER C_(60)/C_(70)-ACRYLIC ACID(ESTER)

作　　者：刘晓国[1] 官文超[1] 李贤[2] 

机构地区：[1]华中科技大学材料学院,湖北武汉430074 [2]广州大学生化学院,广东广州510091

出　　处：《高分子材料科学与工程》2003年第5期57-60,共4页Polymer Materials Science & Engineering

摘　　要：将纳米C60/C70与丙烯酸(酯)单体在引发剂作用下共聚,合成得到C60/C70-丙烯酸(酯)共聚物。对该共聚物的结构进行了红外光谱和荧光光谱分析,探讨了有富勒烯参与的聚合反应机理和共聚物结构。将该共聚物用有机胺中和成盐,使其水性化,制得水溶性纳米C60/C70-丙烯酸(酯)高分子成膜材料,对其成膜性能进行了分析测试。发现C60/C70对丙烯酸(酯)聚合物具有独特的成膜改性功能。Nanometer C60/C70 and monomers of acrylic acid (ester) were copolymerized with initiator to synthesize, the polymer of nanometer C60/C70acrylic acid (ester). Its structure and the synthesis mechanism were analyzed by infrared and fluorescence spectroscopy. And then watersoluble membraneforming polymer of nanometer C60/C70acrylic acid (ester) was synthesized with hydration. Its membraneforming properties were determined. The results indicate that C60/C70 has unique effect on improving properties of acrylic acid polymer.

关 键 词：纳米C60/C70-丙烯酸酯共聚物 合成 性能 引发剂 红外光谱 荧光光谱 

分 类 号：TQ325.7[化学工程—合成树脂塑料工业]