Fabrication of Ormocer Containing Eu^(3+) Ion and Their Optical Spectra  

作　　者：夏海平 宋宏伟 章践立 王金浩 聂秋华 张家骅 

机构地区：[1]Key Laboratory of Photo Electronic Materials, Ningbo University [2]Key Laboratory of Excited State Physics, Changchun Institute of Optics, Fine Machine and Physics, Chinese Academy of Sciences

出　　处：《Journal of Rare Earths》2003年第3期318-321,共4页稀土学报（英文版）

基　　金：ProjectsupportedbytheNationalScienceFoundationofChina ( 60 2 72 0 3 4) ;theNaturalScienceFoundationofZhejiangProvince ( 5 0 2 164 )

摘　　要：Eu 3+ ions were incorporated in sol and gel by a sol gel processing using 3 glycidoxypropyltrimethoxysilane (CH 2OCHCH 2O(CH 2) 3Si(OCH 3) 3, GPTMS) and ethyl silicate (TEOS) as precursors. The basic chemical physical properties such as DTA curve, FT IR spectra and specific surface area were recorded. The characteristics of their optical spectra were measured and investigated. The results indicate that the emission intensity of Eu 3+ ion in ormocer is much higher and the global line width is wider than those in SiO 2 gel. The relationship between the composition and structure of gels and the fluorescence intensity and width were discussed. The obtained ormocer shows good mechanical strength, which can be cut and polished in machine without broken.Eu 3+ ions were incorporated in sol and gel by a sol gel processing using 3 glycidoxypropyltrimethoxysilane (CH 2OCHCH 2O(CH 2) 3Si(OCH 3) 3, GPTMS) and ethyl silicate (TEOS) as precursors. The basic chemical physical properties such as DTA curve, FT IR spectra and specific surface area were recorded. The characteristics of their optical spectra were measured and investigated. The results indicate that the emission intensity of Eu 3+ ion in ormocer is much higher and the global line width is wider than those in SiO 2 gel. The relationship between the composition and structure of gels and the fluorescence intensity and width were discussed. The obtained ormocer shows good mechanical strength, which can be cut and polished in machine without broken.

关 键 词：organic chemistry Eu    3+   ion ORMOCER optical spectra rare earths 

分 类 号：O482.31[理学—固体物理]