Phase Chemistry of the Complexes of RE Amino Acids  

作　　者：高胜利 陈三平 李焕勇 Yang Xuwu杨旭武 史启祯 

机构地区：Department of Chemistry, Shaanxi Key Laboratory of Physico-Inorganic Chemistry, Northwest University, Xi′an 710069, China

出　　处：《Journal of Rare Earths》2002年第1期1-9,共9页稀土学报（英文版）

基　　金：the National Natural Science Foundation of China，山西省自然科学基金

摘　　要：Forty three phase diagrams of ternary system concerning rare earth salts, α amino acids and water, which were constructed by phase equilibrium methods, were expounded. The influences of the factors such as cations, anions, the structure of amino acids, temperature on the phase diagrams were discussed. Under the guidance of phase equilibrium results, over 150 new solid complexes were prepared. IR, reflecting, UV, FS, and Raman spectra for these complexes were investigated and the regularity of 'tripartite effect', 'tetrad effect', 'Nephelanxetic effect', 'Oddo Harkins' was observed. Thermal decomposition processes of the complexes were confirmed. Based on the comparison with the known crystal structures of rare earth amino acid complexes, an estimation method for predicting the crystal structure data of series complexes was founded. The constant volume combustion energies of the complexes were determined by RBC 1 type rotating bomb calorimeter. The standard enthalpies of combustion and standard enthalpies of formation were calculated for these complexes.Forty three phase diagrams of ternary system concerning rare earth salts, α amino acids and water, which were constructed by phase equilibrium methods, were expounded. The influences of the factors such as cations, anions, the structure of amino acids, temperature on the phase diagrams were discussed. Under the guidance of phase equilibrium results, over 150 new solid complexes were prepared. IR, reflecting, UV, FS, and Raman spectra for these complexes were investigated and the regularity of 'tripartite effect', 'tetrad effect', 'Nephelanxetic effect', 'Oddo Harkins' was observed. Thermal decomposition processes of the complexes were confirmed. Based on the comparison with the known crystal structures of rare earth amino acid complexes, an estimation method for predicting the crystal structure data of series complexes was founded. The constant volume combustion energies of the complexes were determined by RBC 1 type rotating bomb calorimeter. The standard enthalpies of combustion and standard enthalpies of formation were calculated for these complexes.

关 键 词：Key word: rare earths amino acids phase chemistry THERMOCHEMISTRY 

分 类 号：O623[理学—有机化学]