Oxidation of n-Butanol and 2-Pentanol with Molecular Oxygen in Supercritical CO2  

作　　者：Yan Hong CHANG, Tao JIANG, Liang GAO, Quo Ying ZHAO, Hai Xiang GAO, Zhong Hao LI, Jun Chun LI, Zhi Min Liu, Bu Xing HANCenter for Molecular Sciences, Institute of Chemistry, Chinese Academy of Sciences,Beijing 100080 

出　　处：《Chinese Chemical Letters》2003年第10期1070-1072,共3页中国化学快报（英文版）

基　　金：supported by National Natural Science Foundation of China(20073056).

摘　　要：Oxidation of n-butanol and 2-pentanol using molecular oxygen in supercritical (SC) CO2 with and without co-solvent is investigated. The results showed that the reaction selectivity is high when the reaction is carried out in SC CO2. It has been observed that co-solvent affects conversion and selectivity of the reaction considerably.Oxidation of n-butanol and 2-pentanol using molecular oxygen in supercritical (SC) CO2 with and without co-solvent is investigated. The results showed that the reaction selectivity is high when the reaction is carried out in SC CO2. It has been observed that co-solvent affects conversion and selectivity of the reaction considerably.

关 键 词：Oxidation n-butanol 2-pentanol supercritical CO2 co-solvent. 

分 类 号：O621.25[理学—有机化学]