Reductive Deoxygenation of Carbonyl to Methylene by LiAlH4/InBr3  

Reductive Deoxygenation of Carbonyl to Methylene

作　　者：Nan Yan FU, Xue Mei ZHAO, Yao Feng YUAN, Ji Tao WANGDepartment of Chemistry, National Key Laboratory of Elemento-organic Chemistry, Nankai University, Tianjin 300071 

出　　处：《Chinese Chemical Letters》2003年第10期1018-1020,共3页中国化学快报（英文版）

基　　金：the National Natural Science Foundation of China(29872018&29972026);the Key Laboratory of Elemento-oiganic Cheraistiy,Nankai University and RFDP,China's Ministry of Higher Education(1999005520)for their financial support

摘　　要：The reductive deoxygenation of aldehydes and ketones into the corresponding alkanes is accomplished by LiAlH4, in the presence of Lewis acid InBr3. It provides a convenient method to complete the transformation from carbonyl compounds to alkanes.The reductive deoxygenation of aldehydes and ketones into the corresponding alkanes is accomplished by LiAlH4, in the presence of Lewis acid InBr3. It provides a convenient method to complete the transformation from carbonyl compounds to alkanes.

关 键 词：Indium (III) tribromide lithium aluminium hydride reductive deoxygenation. 

分 类 号：O621[理学—有机化学]