聚硅氧烷冠醚做气相色谱固定液的研究  

The Investigation of Poly (Crown Ether )Siloxane as a Gas Chromatographic Stationary Phase

作　　者：傅若农[1] 张爱琴[1] 葛纪龙 邓景辉[1] 金永浩[1] 朱济亚 顾俊岭[1] 黄载福[2] 张斌[2] 

机构地区：[1]北京理工大学化工系,100081 [2]武汉大学环科系,430072

出　　处：《色谱》1992年第4期199-203,共5页Chinese Journal of Chromatography

基　　金：国家自然科学基金

摘　　要：自从Pedersen首次发现冠醚能和金属离子形成稳定的络合物之后,冠醚在分析化学中得到了广泛的应用。它在液相色谱中的应用开发较早。低分子冠醚在气相色谱中的应用在1985年首先由李如松报道。Zagorevskaya等人则把低分子冠醚涂渍在碳分子筛上分离各种烷烃、芳烃和含氯化合物。Three new kinds of poly (crown ether)siloxane and three low-molecular-weight crown ethers have been used as stationary phases of open-tubular gas chromatographic column. The fused silica capillary columns coated with the poly (crown ether ) siloxanes possess high efficiency, high thermostability and good selectivity. These columns are suitable for separation of alcohols and phenols, for example, 9 isomers of cresol and dimethylphenol can be separated successfully on the PSO-DB-14C4 column.

关 键 词：聚硅氧烷冠醚 气相色谱 固定液 

分 类 号：O657.71[理学—分析化学]