N-[(2-羟基-5-甲基苯)(苯基)]亚甲基邻苯二胺的晶体结构及电极反应  

The Crystal Structure and Elec trode Reaction of N-［(2-hydroxy-5-methylphenyl) (phenyl)］ Methylene-o -Phenylenediamine

作　　者：王进义[1] 程东亮[1] 

机构地区：[1]兰州大学应用有机化学国家重点实验室,甘肃兰州730000

出　　处：《兰州大学学报（自然科学版）》2000年第6期61-65,共5页Journal of Lanzhou University(Natural Sciences)

基　　金：国家自然科学基金!(29772010)

摘　　要：合成了N-［(2-羟基-5-甲基苯)（苯基）］亚甲基邻苯二胺，晶体属单斜晶系，空 间群P21/c. 晶胞参数 a = 1.034 0(6) nm， b =1.092 0(3) nm， c =1.472 0(4) nm, β = 107.89(3)°, 化学式C20H18N2O, M r =302.36， Z =4, V =1.581 7(10) nm3 ， D c = 1.268 g/cm3， F （000）= 160，最终偏离因子 R1 = 0.054 1. 结构分析表明，分子间以氢键形成二聚体，二聚体 的分子间互为中心对称. 循环伏安法表明标题化合物的电极反应是一个不可逆的单电子传荷 过程.The crystal structure of the compound N-［(2-hydroxy-5-methylphenyl) (phenyl)］ methylene- o -ph enylenediamine(C20H18N2O), has been determined by single crystal X -ray diffraction at 300 K. The crystal is monoclinic, space group P21/c, with a =1.034 0(6) nm, b =1.092 0(3) nm, c =1.472 0(4) nm, β =107.89(3) °, V =1.581 7(10) nm3, D c =1.268 g/cm3, F (000)=160, Z =4. The final refinement is converged with R1 =0.054 1 for 182 5 observed r eflections ［ I>2σ(I) ］. The result of structure analysis indicates that the dipolymer is formed by intermolecular H-bond. Cyclic voltammetry shows that th e electrode reaction is a irreversible single electrotransfer one.

关 键 词：N-[(2-羟基-5-甲基苯)(苯基)]亚甲基邻苯二胺 晶体结构 循环伏安 

分 类 号：O611.4[理学—无机化学]