Kinetics and Mechanism of Bulk Polymerization of Styrene Catalyzed by Rare Earth Catalyst  

作　　者：吴林波 李伯耿 李宝芳 曹堃 

出　　处：《Chinese Journal of Chemical Engineering》2001年第4期376-381,共6页中国化学工程学报（英文版）

基　　金：Supported by the National Natural Science Foundation of China (No. 29734130).

摘　　要：The bulk polymerization of styrene catalyzed by Nd(P204)3/MgBu2/HMPA (hexamethyl phospho-ramide) was carried out in capped glass tubes. The effects of reaction conditions on polymerization conversion and molecular weight in the range of high conversion were investigated. The molecular weight of the resultant polymers is dramatically high and its distribution is relatively narrow. The polymerization process demonstrates the feature of living polymerization and auto-acceleration phenomenon. The auto-acceleration phenomenon is attributed to the non-instantaneous formation of the active species. The experimental data suggest that chain transfer to MgBu2 is one of the factors governing the molecular weight development. A mechanism of polymerization is presented with the chain transfer process incorporated.The bulk polymerization of styrene catalyzed by Nd(P204)3/MgBu2/HMPA (hexamethyl phospho-ramide) was carried out in capped glass tubes. The effects of reaction conditions on polymerization conversion and molecular weight in the range of high conversion were investigated. The molecular weight of the resultant polymers is dramatically high and its distribution is relatively narrow. The polymerization process demonstrates the feature of living polymerization and auto-acceleration phenomenon. The auto-acceleration phenomenon is attributed to the non-instantaneous formation of the active species. The experimental data suggest that chain transfer to MgBu2 is one of the factors governing the molecular weight development. A mechanism of polymerization is presented with the chain transfer process incorporated.

关 键 词：STYRENE POLYMERIZATION rare earth catalyst KINETICS MECHANISM 

分 类 号：TQ325[化学工程—合成树脂塑料工业]