Sm/AlCl3·6H2O体系促进的叠氮化合物的化学选择性还原:一种制备胺的新方法  

Chemoselective Reduction of Azides Promoted by Sm/AlCl_3·6H_2O System:A New Method to Prepare Amines

作　　者：张纪明[1] 张永敏[1] 

机构地区：[1]浙江大学西溪校区化学系,浙江杭州310028

出　　处：《合成化学》2002年第6期498-500,503,共4页Chinese Journal of Synthetic Chemistry

基　　金：the National Natural Science Foundation of China(Project No.29872010);Natural Science Foundation of Zhejiang Province for financial support.

摘　　要：在金属钐和六水合三氯化铝的存在下 。In the presence of metallic samarium-aluminum(Ⅲ) chloride hexahydrate, azides can be reduced to corresponding amines in high yields under mild and neutral conditions.

关 键 词：叠氮化合物 胺 金属钐 六水合三氯化铝 还原 

分 类 号：O625.6[理学—有机化学] O621.[理学—化学]