活性炭负载FeCl_3催化合成CH_3COOEt的研究  

Synthesis of ethyl acetate catalyzed with active carbon supported ferric chloride

作　　者：贾树勇[1] 任玉荣[1] 张首才[1] 马春宏[2] 隋长青[1] 

机构地区：[1]吉林师范大学化学学院吉林师范大学应用化学研究所,吉林四平136000 [2]吉林师范大学教务处,吉林四平136000

出　　处：《宝鸡文理学院学报（自然科学版）》2003年第4期279-280,283,共3页Journal of Baoji University of Arts and Sciences(Natural Science Edition)

摘　　要：以活性炭负载氯化铁(FeCl3/C)为催化剂,冰乙酸和无水乙醇为原料合成了乙酸乙酯,考察了适宜反应条件。结果表明,冰乙酸用量为0.20mol,乙醇用量为0.60mol,催化剂用量为3.0g,反应时间为1.5h时,乙酸酯化率达84.97%。Based on the synthesis of ethyl acetate by using active carbon supported ferric chloride as catalyst, acetic acid and ethanol as materials, the optimal conditions were determined. The results show that the ratio of esterification reaches 84.97%,when 0.20 mol acetic acid, 0.60 mol ethanol and 3.0 g the catalyst are used and the reaction time is 90 mins.

关 键 词：氯化铁 催化 合成 乙酸乙酯 

分 类 号：O621.36[理学—有机化学]