金属化的苄叉基膦叶立德与羰基化合物的Wittig反应的立体化学(英文)  

Stereochemistry of Wittig Reactions of Metalated Benzylidene Phosphonium Ylide With Carbonyl Compounds

作　　者：石德清[1] 黄文芳[1] 丁明武[1] 吴田捷[1] 

机构地区：[1]华中师范大学化学学院,湖北武汉430079

出　　处：《合成化学》2003年第6期507-508,共2页Chinese Journal of Synthetic Chemistry

基　　金：HubeiNaturalScienceFoundationforfinancialsupport(2 0 0 0J0 1 4)

摘　　要：首次系统报道了金属化的苄叉二苯基膦烷与芳香醛、酮的Wittig的立体化学 ,与相应的单叶立德相比 ,反应具有高的立体选择性、反应活性和较好的原子经济性的优点。The stereochemistry of Wittig reactions of metalated benzylidene diphenyl phosphorane with aromatic aldehydes and ketones were investigated for the first time, the reactions of metalated ylide(diylide) show higher stereoselectivity and nucleophilicity and good atomic economy in comparison with that of the corresponding monoylid.

关 键 词：立体化学 金属化苄叉基膦叶立德 WITTIG反应 

分 类 号：O627.5[理学—有机化学]