氨络合物体系中镍在玻璃碳上的电化学成核机理  

Electrochemical Nucleation of Nickel on Vitreous Carbon in Leaching Solution Containing Ammonia and Chloride

作　　者：郑利峰[1] 郑国渠[1] 曹华珍[1] 张九渊[1] 

机构地区：[1]浙江工业大学材料科学与工程研究所,浙江杭州310014

出　　处：《材料科学与工程学报》2003年第6期882-885,共4页Journal of Materials Science and Engineering

基　　金：国家自然科学基金资助项目 (50 0 4 0 0 5)

摘　　要：采用循环伏安法和计时电流法研究了氨络合物体系中镍在玻璃碳上电结晶的初期行为。结果表明 ,镍在该基体上的沉积没有经历UPD过程 ,镍的电沉积经历了晶核形成过程 ,在所研究的外加电位范围内其电结晶按连续成核和三维生长方式进行 ,外加电位对晶体生长具有显著的影响。通过分析恒电位暂态曲线 ,求出镍离子的扩散系数D ,以及不同外加电位下的饱和晶核数密度Nsat。Initial stages of electrocrystallization of nickel on vitreous carbon from a leaching solution containing ammonia and chloride were investigated by means of cyclic voltammetric and chronoamperometric technique.The results show that the deposition of nickel on the substrate did not undergo UPD process,but undergoes nucleation process.In the experimental conditions,the electrocrystallization of nickel follows the mechanism of three dimensional progressive nucleation and growth.By analyzing of the potentiostatic transients,the diffusion coefficient D of the depositing nickel ions and saturated nuclear number density N sat were estimated,the effects of applied potential on nucleation and growth were also discussed.

关 键 词：镍 循环伏安法 计时电流法 氨络合物体系 电结晶 电化学成核机理 

分 类 号：O614.813[理学—无机化学] O74[理学—化学]