溶液体系配合物稳定常数间定量关系的研究进展(Ⅱ)——配合物稳定常数间的定量关系  

The Research Advance of Quantitative Relationships among the Stability Constants of Complexes in Solution System

作　　者：郭峰[1] 朱元成[1] 董晓宁 

机构地区：[1]天水师范学院化学系,甘肃天水741001 [2]兰州农业学校,甘肃兰州730020

出　　处：《天水师范学院学报》2003年第5期29-31,共3页Journal of Tianshui Normal University

摘　　要：配合物稳定常数的应用日趋广泛，研究表明在相关联的配合物稳定常数间也存在定量的经验关系。通过配合物稳定常数间的直线自由能关系、logK与logKM(OH) 之间的线性关系、Irving-Williams 序列关系、稳定常数与Lewis酸碱参数的关系、镧系及锕系元素碳酸配合物稳定常数的计算等定量关系分析，表明溶液体系中配位化学的研究进展。By analyzing the quantitative relationships existing among stability constants, such as the Linear Free Energy Relationship (LFER), the linear relationship between logK and logKM(OH), irving-Williams order, the degree of stability constants relied on the acid-base parameter, and the stability constant's computation of lanthanide and actinoid complexes containing carbonate ion, the advance in coordination chemistry in solution systems has been reviewed with 10 references.

关 键 词：溶液体系 稳定常数 定量关系 配合物 配位化学 直线自由能关系 

分 类 号：O641.4[理学—物理化学] O645.1[理学—化学]