CoC_(60)(OH)的合成及氧化还原性能  

Synthesis and Redox Behavior of Complex CoC_(60)(OH)

作　　者：吴振奕[1] 杨森根[1] 林永生[1] 程大典[1] 詹梦熊[1] 

机构地区：[1]厦门大学化学系,厦门361005

出　　处：《应用化学》2004年第1期81-83,共3页Chinese Journal of Applied Chemistry

基　　金：福建省自然科学基金 (E0 110 0 0 2 );高等学校博士学科点专项科研基金(980 3 8410);厦门大学校级自选课题基金资助项目

摘　　要：The fullerene compound CoC 60(OH) has been prepared by the reaction of C - 60 anion with Co(Ⅱ) hydrous salt under nitrogen atmosphere and refluxing, and the title compound is characterized by FAB-MS, elemental analysis, FT-IR, XPS, UV-Vis and 1H NMR. The results prove the presence of C-Co and -OH groups in the resultant, and coovalent of Co bonding to C 60. The apparent charge distribution of the resultant appeaers to be Co 2+C - 60(OH) -, and there are three kinds of carbons with different electron density. The result of redox experiment indicates that the reduction potential of the compound is more negative than that of pure C 60.The fullerene compound CoC 60(OH) has been prepared by the reaction of C - 60 anion with Co(Ⅱ) hydrous salt under nitrogen atmosphere and refluxing, and the title compound is characterized by FAB-MS, elemental analysis, FT-IR, XPS, UV-Vis and 1H NMR. The results prove the presence of C-Co and -OH groups in the resultant, and coovalent of Co bonding to C 60. The apparent charge distribution of the resultant appeaers to be Co 2+C - 60(OH) -, and there are three kinds of carbons with different electron density. The result of redox experiment indicates that the reduction potential of the compound is more negative than that of pure C 60.

关 键 词：C60 合成 氧化还原性 

分 类 号：O621.3[理学—有机化学] O622.6[理学—化学]