复合添加剂焙烧-稀酸浸出清洁提钒工艺研究  

Study on Environment-friendly Vanadium Extraction Process by Roasting with Composite Additives and Leaching with Dilute Acid

作　　者：蔡俊[1] 颜文斌[1] 华骏[1] 高峰[1] 易静[1] 何新波[2] 

机构地区：[1]吉首大学化学化工学院,湖南吉首416000 [2]北京科技大学材料科学与工程学院,北京100083

出　　处：《稀有金属与硬质合金》2015年第4期10-12 33,共4页Rare Metals and Cemented Carbides

基　　金：国家科技支撑计划项目(2012BAE06B04);湖南省高校科技创新团队支持计划"环境能源材料与武陵山区矿产资源精深加工"项目

摘　　要：采用复合添加剂焙烧-稀酸浸出工艺提钒,考察了复合添加剂用量、焙烧温度、焙烧时间、硫酸用量、浸出时间、浸出温度及液固比对钒浸出率的影响。结果表明,在复合添加剂用量6%、焙烧温度800℃、焙烧时间3h,硫酸用量3%、浸出时间3h、浸出温度60℃和液固比3∶1的条件下,钒浸出率为85.6%,比钙化焙烧工艺的钒浸出率提高了13.4%。本工艺焙烧过程中产生的烟气污染较小,对环境相对友好,且能大幅度提高钒浸出率。Vanadium was extracted by roasting with composite additives and leaching with dilute acid.Impacts were investigated of composite additive dosage,roasting temperature,roasting duration,sulfuric acid dosage,leaching duration,leaching temperature and liquid-solid ratio on vanadium leaching rate.The results show that under the conditions of composite additive dosage 6%,roasting temperature 800 ℃,roasting duration 3h,sulfuric acid dosage 3%,leaching duration 3h,leaching temperature 60℃and liquid-solid ratio 3∶1,the vanadium leaching rate of the above process is85.6%,increased by 13.4%compared with that of calcification roasting process.This technology has a good application prospect as an environment-friendly process with less off-gas pollution during roasting and substantially improved vanadium leaching rate.

关 键 词：清洁提钒 复合添加剂 焙烧 酸浸 

分 类 号：TF841.3[冶金工程—有色金属冶金]