一种判断有机立体化学反应产物结构的简单方法  

Predicting the Product Structure in Organic Stereospecific Reaction with a Simple Method

作　　者：赵胜芳[1] 陈年友[1] 吕守茂[2] 

机构地区：[1]黄冈师范学院化学系,湖北黄冈438000 [2]咸宁学院,湖北咸宁437005

出　　处：《孝感学院学报》2003年第6期45-47,共3页JOURNAL OF XIAOGAN UNIVERSITY

摘　　要：归纳了烯烃的加成、醇及卤代烃等化合物的β 消去、周环反应等反应产物的立体结构与反应物结构和反应历程的关系,探索出一种用简单的数学方法推知这些有机立体化学反应产物结构的方法。By analysing stereo-structures of the reaction products in several types of reactions,such as addition reation of alkene,β-elimination reaction of alcohol and the halohydrocabon,pericyclic reaction,we summarized the relationship between reactant structures and reaction mechanisms.Based on the summarization,we concluded a convenient algebraic method which can be used to predict the product stereo-structures in these reactions.

关 键 词：有机立体化学 反应产物 立体结构 反应物结构 β-消去反应 反应历程 周环反应 

分 类 号：O621.13[理学—有机化学]