含Ph2PPy配体的络合物的合成及催化性能  

Synthesis and catalytic properties of some mononuclear and dinuclear complexes containing diphenylpyridylphosphine（Ph2PPy）

作　　者：赵维君[1] 方延铨[1] 张书笈[1] 张正之[1] 杨丽梅[1] 

机构地区：[1]南开大学化学系

出　　处：《天然气化工—C1化学与化工》1992年第4期3-6,共4页Natural Gas Chemical Industry

摘　　要：合成了二苯基吡啶基膦配体（Ph2PPy）,以及该配体与Fe、Co、Ni等单核和Fe-Rh、Co-Rh、Ni-Rh等双核络合物。评价了这些络合物催化剂对甲醇羰基化反应的催化性能。A ligand diphenylpyridylphosphine(Ph_2PPy), some mononuclear complexes from the ligand and Fe,Co,Ni and dinuclear complexes from the ligand and Fe-Rh,Co-Rh,Ni-Rh have been synthesized. The catalytic properties of these complexes for the reaction of carbonylation of methanol are evaluated.

关 键 词：PH2PPY 络合物 催化性能 催化剂 

分 类 号：O643.36[理学—物理化学]