最小自由能法求解GAP在等压绝热条件下的燃烧产物  

Free-Energy Minimization Investigation on Combustion of GAP Under Constant Pressure and Adiabatic Condition

作　　者：王天放[1] 李疏芬[1] 

机构地区：[1]中国科技大学化学物理系,安徽合肥230026

出　　处：《火炸药学报》2003年第4期16-19,共4页Chinese Journal of Explosives & Propellants

基　　金：国家自然科学基金资助项目(50176047)

摘　　要：采用最小自由能法计算了GAP在等压绝热条件下的燃烧温度以及产物的比例,从理论上说明了GAP的燃烧特点。计算结果显示,GAP燃烧产物中有较多的固态C、气态H2、CO等可以再燃烧的物质存在。The principle of free-energy minimization is used to calculate the properties of combustion of glycidyl azide polymer (GAP) under isotonit and adiabatic conditions such as the combustion temperature and the ratio of products. The calculated results show that there are relatively large numbers of H2(g), CO(g) and C(s) in the combustion products of GAP.

关 键 词：最小自由能法 GAP 燃烧产物 推进剂 含能粘合剂 

分 类 号：O643.21[理学—物理化学]