铜(Ⅱ)与N(2-羟基乙基)水杨醛亚胺配合物的合成、结构和热分解  

SYNTHESIS, STRUCTURE AND THERMAL DECOMPOSITION OF THE COMPLEX OF Cu(II) WITH N(2-HYDROXYETHYL) SALICYLALDIMINO

作　　者：崔学桂[1] 刘德信[1] 李晓燕[1] 孙宏建[1] 李凤玲[1] 许义斌[2] 林秀云[2] 林政炯[2] 

机构地区：[1]山东大学应用化学系,济南250100 [2]中国科学院生物物理研究所,北京100080

出　　处：《无机化学学报》1992年第3期329-332,共4页Chinese Journal of Inorganic Chemistry

摘　　要：人们在探索新的有效抗癌药物时,发现了一些Schiff碱及其和某些金属生成的配合物具有抗癌作用。为研究此类配合物的抗癌作用和结构的关系,我们合成了一系列Schiff碱类配合物。 本文合成了Cu(Ⅱ)与N(2-羟基乙基)水杨醛亚胺配合物,培养出了单晶,通过X射线单晶衍射确定了配合物的晶体和分子结构,并对其热分解过程进行了初步探讨。The complex of Cu(II ) with N(2-hydroxyethyl) salicyldimino Cu(OC6H4CHNCH2-CH2OH)2 was perpared. Its structure was determined by means of four-cycle diffractometer. It was found that the crystal belongs to the monoclinic system with group P21, and the unit ceil parameters are: a=18.302A, b = 4.806A, c= 19.781 A, β=98.87°, V= 1718A3, Z=4, Mr=391.9, Dc= 1.52g/cm3, F(000) = 820. The structure was solved by direct method and the final R = 0.076. The process of its thermal decomposition was investigated by means of DTA and TG techniques.

关 键 词：铜 结构 热分解 络合物 

分 类 号：O614.121[理学—无机化学]