硫物种对负载型钯催化剂上氢吸附性质的影响  

EFFECT OF SULFUR SPECIES ON H_2 ADSORPTION ON SUPPORTED PALLADIUM CATALYST

作　　者：肖天存[1] 安立敦[1] 张兵[1] 蒋致诚[1] 

机构地区：[1]中国科学院兰州化学物理研究所,兰州730000

出　　处：《物理化学学报》1992年第4期470-475,共6页Acta Physico-Chimica Sinica

基　　金：国家自然科学基金

摘　　要：用X光光电子能谱(XPS)分析了负载型Pd/Al_2O_3催化剂上硫和钯的状态。以程序升温脱附-质谱(TPD-MS)方法研究了不同硫物种及不同气氛对催化剂氢吸附性质的影响。结果表明:硫物种对氢吸附的影响按S_2^(2-)、S^(2-)、SO_4^(2-)的顺序减小,且前两者的影响远比SO_4^(2-)的大。这与催化剂在H_2-O_2反应中的抗硫性评价结果一致。并用原子分子轨道理论对上述结果进行了讨论。A series of supported palladium catalysts were prepared with impregnating method. SO_4^(2-) was introduced by dipping Al_2O_3 into dilute H_2SO_4 solution for the preparation of Pd/Al_2O_3--SO_4 or impregnating Pd/Al_2O_3 with a series of K_2SO_4 solutions for Pd/SO_4^(2-)/Al_2O_3 as catalysts. X-ray photoelectron spectroscopy was employed tomeasure the states of sulfur and palladium before and after the catalysts were treatedunder different atmospheres. Temperature programmed desorption-mass spectroscopy(TPD-MS) was used to investigate the effect of different sulfur species and atmo-sphere on H_2 adsorption on the catalysts.The results showed as follows: The influen-ce of sulfur species upon H_2 desorption declined in a order as S_2^(2-),S^(2-) and SO_4^(2-),and tbe effeet of the former two was more distinct than SO_4^(2-). Their behaviors werein accord with the evaluation of the catalyst for H_2-O_2 reaction, which may be in-terpreted with the molecular orbital theory.

关 键 词：负载型 硫物种 吸附 氢 钯催化剂 

分 类 号：O613.2[理学—无机化学]