对甲基苯磺酰氯催化α-萘乙酸甲酯的合成  

Catalytic synthesis of methyl a-naphthyl acetate with p-tolu-ene sulfochloride

作　　者：靳通收[1] 马志刚[1] 张建设[1] 

机构地区：[1]河北大学化学与环境科学学院,河北保定071002

出　　处：《化学试剂》2003年第6期357-358,360,共3页Chemical Reagents

基　　金：国家自然科学基金项目(29872011);教育部高等学校骨干教师资助项目

摘　　要：以对甲基苯磺酰氯为催化剂,α-萘乙酸和甲醇为原料,经酯化直接合成了α-萘乙酸甲酯。研究了催化剂的用量、酸醇比、反应温度及反应时间等因素对反应的影响,通过实验优化,其最佳反应条件:催化剂用量为原料质量的2.8％,酸醇物质的量比为1:10,反应温度80～85℃,反应时间30min。酯的产率为97.2％。In this paper, we have developed a method for the preparation of methyl a-naphthylacetate from a-naphthylacetic acid and methanol as the starting materials catalyzed by TsCl. The optimum reaction conditions of the preparation of methyl a-naphthylacetate, including reaction temperature, reaction time, molar ratio of reactants, quantity of catalyst were determined. Yield of the product was 97. 2%. The results of IR spectra and HNMR spectra indicated that the product was methyl a-naphthylacetate.

关 键 词：α—萘乙酸甲酯 对甲基苯磺酰氯 合成 催化剂 植物生长调节剂 

分 类 号：TQ452[化学工程—农药化工]