Synthesis and Crystal Structure of a Puckered Rhombus Grid-like Coordination Polymer with Bridging Ligand Containing Sulfanyl Linker  

作　　者：韩磊 罗军华 洪茂椿 王瑞虎 林郑忠 曹荣 

机构地区：[1]State Key Laboratory of Structural Chemistry,Fujian Institute of the Research on the Structure of Matter,Chinese Academy of Sciences

出　　处：《Chinese Journal of Chemistry》2004年第1期51-54,共4页中国化学（英文版）

基　　金：the National Natural Science Foundation of China (No. 20231020), the Natural Science Foundation of Fujian Province and Chinese Academy of Sciences.

摘　　要：A new coordination polymer with sulfide moieties, [Co(ptmb)2]·0.25H2O (ptmb=4-(4-pyridylthiomethyl)-benzoate), was synthesized by self-assembly of Co(NO3)2·6H2O with Hptmb under solvothermal conditions. X-ray single crystal diffraction study shows that it is a 2D layer structure consisting of puckered rhombus grid with di-mensions 1.175 nm×1.110 nm.A new coordination polymer with sulfide moieties, [Co(ptmb)2]·0.25H2O (ptmb=4-(4-pyridylthiomethyl)-benzoate), was synthesized by self-assembly of Co(NO3)2·6H2O with Hptmb under solvothermal conditions. X-ray single crystal diffraction study shows that it is a 2D layer structure consisting of puckered rhombus grid with di-mensions 1.175 nm×1.110 nm.

关 键 词：crystal structure coordination polymer solvothermal synthesis sulfide moiety 

分 类 号：O641.4[理学—物理化学]