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作 者:李伟[1] 宋春花[1] 包鹏[1] 马骏[1] 朱劲松[1] 王业宁[1]
机构地区:[1]南京大学物理系固体微结构国家重点实验室,南京210093
出 处:《金属学报》2003年第11期1197-1200,共4页Acta Metallurgica Sinica
基 金:国家自然科学基金基目90207027;国家重点基础研究发展规划项目2002CB613300资助
摘 要:用传统的固相反应方法制备了CuFe2O4-Pb(Mg1/3Nb2/3)O3复合体材料陶瓷.用X射线衍射确定了复合体材料中各相的存在.用双端振动簧法研究了样品在-200-400℃的音频内耗谱,在37.6℃发现一个很大的内耗峰P1,并伴随着约9%的模量的软化,表明了相变的存在.在室温下,测量了介电常数ε’和介电损耗tanδ随频率变化的关系;同时,测量了复合体材料的介电常数和介电损耗随温度的变化关系,进一步验证P1峰由立方到四方的相变引起.最后给出样品的磁滞回线.CuFe2O4-Pb(Mg1/3Nb2/3)O-3 composites were prepared using conventional solid state reaction method. The presence of both phases in the composites was confirmed by X-ray diffraction. The internal friction was measured using the vibrating reed method from -200-400 degreesC at kilohertz frequency, an internal friction peak was observed around 37.6 degreesC, accompanied with an about 9% modulus softening, which reveals a phase transition. Variations of dielectric constant and loss tangent with frequency and temperature under different frequencies were studied, further confirmed the peak P-1 is related to a phase transition (tetragonal to cubic). Magnetic hysteresis loops of the samples were also given out.
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