微波照射下H_2O_2氧化1,2-环己二醇合成己二酸(英文)  

Synthesis of Adipic Acid from 1,2-Cyclohexanediol with H_2O_2 under Microwave Irradiation

作　　者：周民锋[1] 纪顺俊[1] 黄晓英[1] 

机构地区：[1]苏州大学化学化工学院,江苏苏州215006

出　　处：《合成化学》2004年第1期9-11,共3页Chinese Journal of Synthetic Chemistry

基　　金：theNationalNaturalScienceFoundationofChina( 2 0 1 72 0 3 9)

摘　　要：以钨酸钠为催化剂在微波照射条件下 ,用 3 0 %H2 O2 使 1 ,2 己二醇氧化开环合成己二酸。考察了照射时间、溶液pH值、不同催化剂及催化剂循环使用等对反应的影响 ,找出了反应的最佳条件。Adipic acid was synthesized from 1,2-cyclohexanediol with 30% H 2O 2 using Na 2WO 4·2H 2O as a catalyst under microwave irradiation. The amounts of catalyst, the irradiation time and different catalysts were investigated and the optimum experimental conditions were found.

关 键 词：己二酸 1 2-环己二醇 过氧化氢 微波照射 H2O2 氧化 合成 

分 类 号：O623.613[理学—有机化学]