手性卟啉-尼古丁化合物及其Mn(Ⅲ)配合物的合成  

Synthesis of Chiral Porphyrin-Nicotine Compounds and Their Manganic Complexes

作　　者：闫建辉[1] 韩士田[1] 刘彦钦[1] 

机构地区：[1]河北师范大学化学学院,石家庄050091

出　　处：《应用化学》2004年第3期322-324,共3页Chinese Journal of Applied Chemistry

基　　金：河北省自然科学基金资助项目 (2 0 3 14 7)

摘　　要：Three Mn(Ⅲ) complexes of chiral porphyrin-nicotine compounds were synthesized from tetrasubstited phorphrius and chiral nicotine, as well as maganees acetate in DMF. The complexes were characterized by UV, IR, 1H NMR, MS and elemental analysis. They are expected to have, simultaneously, chiral induction and phase transformation functions for catalysis reactions.Three Mn(Ⅲ) complexes of chiral porphyrin-nicotine compounds were synthesized from tetrasubstited phorphrius and chiral nicotine, as well as maganees acetate in DMF. The complexes were characterized by UV, IR, 1H NMR, MS and elemental analysis. They are expected to have, simultaneously, chiral induction and phase transformation functions for catalysis reactions.

关 键 词：合成 卟啉 尼古丁 金属Mn配合物 

分 类 号：O641.4[理学—物理化学]