Hydrothermal Synthesis and Crystal Structure of a Microporous Gallophosphate with 12-Membered Ring Channels:Ga_9(PO_4)_(12)(H_3TREN)(H_2TREN)_3·xH_2O  

作　　者：CHENXiao-bo LIYi LIGuang-hua DAIZhi-min FUWen-sheng SHIZhan ZHANGDong XUYao-hua FENGShou-hua 

机构地区：[1]StateKeyLaboratoryofInorganicSynthesisandPreparativeChemistry,CollegeofChemistry,JilinUniversity,Changchun130023,P.R.China

出　　处：《Chemical Research in Chinese Universities》2004年第1期24-28,共5页高等学校化学研究（英文版）

基　　金：SupportedbytheNationalNaturalScienceFundationofChina(No.2 0 0 710 13) ,theStateBasicResearchProjectofChina(G2 0 0 0 775 0 7)andFoundationfor"Cheung Kong"ScholarshipbytheMinistryofEducationofChina

摘　　要：An open-framework gallophosphate, Ga_9(PO_4)_ 12[(H_3TREN)(H_2TREN)_3]·xH_2O was hydrothermally synthesized at 453 K with tris(2-aminoethyl) amine(TREN) as the organic template and characterized by single-crystal X-ray diffraction. Ga_9(PO_4)_ 12[(H_3TREN)(H_2TREN)_3]·xH_2O crystallized in a cubic space group I43m, with a=1.68552(3) nm and Z=2. The structure contains 12-membered ring channels and supercages of 1.434 nm in diameter, and is an analogue of Al_9(PO_4)_ 12(C_ 24H_ 91N_ 16)·17H_2O. Template-TREN in the supercage was different from triethylenetetraamine(TETA) used in the initial reaction mixture due to the construction transformation. The TETAs transformed into the TRENs due to the low interaction energy between the template and framework. We verified it via energy calculation and liquid state NMR.An open-framework gallophosphate, Ga_9(PO_4)_ 12[(H_3TREN)(H_2TREN)_3]·xH_2O was hydrothermally synthesized at 453 K with tris(2-aminoethyl) amine(TREN) as the organic template and characterized by single-crystal X-ray diffraction. Ga_9(PO_4)_ 12[(H_3TREN)(H_2TREN)_3]·xH_2O crystallized in a cubic space group I43m, with a=1.68552(3) nm and Z=2. The structure contains 12-membered ring channels and supercages of 1.434 nm in diameter, and is an analogue of Al_9(PO_4)_ 12(C_ 24H_ 91N_ 16)·17H_2O. Template-TREN in the supercage was different from triethylenetetraamine(TETA) used in the initial reaction mixture due to the construction transformation. The TETAs transformed into the TRENs due to the low interaction energy between the template and framework. We verified it via energy calculation and liquid state NMR.

关 键 词：MICROPOROUS GALLOPHOSPHATE HYDROTHERMAL Energy calculation 

分 类 号：O627.32[理学—有机化学]