In-situ FTIR Spectroelectrochemical and Electrochemical Studies of Ferrocene and Derivatives at a Platinum Electrode  

作　　者：PengDu BaoKangJIN JiaXiangYANG XiangQinLIN 

机构地区：[1]DepartmentofChemistry,UniversityofScienceandTechnologyofChina,Hefei230026 [2]SchoolofChemistryandChemicalEngineering,AnhuiUniversity,Hefei230039

出　　处：《Chinese Chemical Letters》2004年第2期204-207,共4页中国化学快报（英文版）

摘　　要：Redox mechanism of ferrocene, acetylferrocene, ferrocenyl cinnamenyl ketone at a platinum electrode was studied with cyclic voltammetry (CV) and in-situ Fourier transform infrared (FTIR) spectroelectrochemistry. The IR bands in the range of 2000-1000 cm-1 attributed to the stretching and ring vibrations of these materials show the main spectral changes in the processes.Redox mechanism of ferrocene, acetylferrocene, ferrocenyl cinnamenyl ketone at a platinum electrode was studied with cyclic voltammetry (CV) and in-situ Fourier transform infrared (FTIR) spectroelectrochemistry. The IR bands in the range of 2000-1000 cm-1 attributed to the stretching and ring vibrations of these materials show the main spectral changes in the processes.

关 键 词：in-situ FTIR spectroelectrochemistry ferrocene(FcH) acetylferrocene(AFc) ferro- cenyl cinnamenyl ketone(FcCK).   I 

分 类 号：O626[理学—有机化学]