原位反应法制备CpTi(dbm)Cl_2/MgCl_2载体型催化剂及其催化乙烯聚合的研究  

In situ SYNTHESIS OF CpTi(dbm)Cl_2/MgCl_2 CATALYST AND ITS CATALYSIS FOR ETHYLENE POLYMERIZATION

作　　者：孙敏[1] 许学翔[1] 赵伟[1] 纪洪波[1] 景振华[1] 

机构地区：[1]石油化工科学研究院,北京100083

出　　处：《高分子学报》2004年第1期137-139,共3页Acta Polymerica Sinica

摘　　要：A novel non metallocene supported catalyst,CpTi(dbm) Cl 2/MgCl 2 was synthesized in situ via reaction between CpTi(dbm)Cl 2 an d BuMgCl in heptane.The surface area,pore volume and crystal structure of the su pported catalyst and MgCl 2(in situ) which was obtained by reaction of Mg a nd BuCl were characterized by BET and XRD methods,respectively.The surface area and pore volume of MgCl 2(in situ) are higher than those of normal MgCl 2,and the s urface area and pore volume of the supported catalyst are also high.The crystal structure of the supported catalyst is amorphous,which is similar to that of MgC l 2(in situ).Ethylene polymerization with MAO or AlR 3 was investigated,w hich indicates that the activity does not decrease while AlR 3 was used as co catalyst instead of MAO,so MAO can be absent in both the catalyst preparation an d et hylene polymerization processes.The catalytic activity can be as high as 3 06× 10\+6gPE/molTi·h with triisobutyl aluminium(Ti BA) as co\|catalyst when polymerization tem perature is 80℃,and Al/Ti molar ratio is 200.A novel non metallocene supported catalyst,CpTi(dbm) Cl 2/MgCl 2 was synthesized in situ via reaction between CpTi(dbm)Cl 2 an d BuMgCl in heptane.The surface area,pore volume and crystal structure of the su pported catalyst and MgCl 2(in situ) which was obtained by reaction of Mg a nd BuCl were characterized by BET and XRD methods,respectively.The surface area and pore volume of MgCl 2(in situ) are higher than those of normal MgCl 2,and the s urface area and pore volume of the supported catalyst are also high.The crystal structure of the supported catalyst is amorphous,which is similar to that of MgC l 2(in situ).Ethylene polymerization with MAO or AlR 3 was investigated,w hich indicates that the activity does not decrease while AlR 3 was used as co catalyst instead of MAO,so MAO can be absent in both the catalyst preparation an d et hylene polymerization processes.The catalytic activity can be as high as 3 06× 10\+6gPE/molTi·h with triisobutyl aluminium(Ti BA) as co\|catalyst when polymerization tem perature is 80℃,and Al/Ti molar ratio is 200.

关 键 词：非茂催化剂 乙烯 聚合反应 原位反应法 制备 负载催化剂 烷基铝 

分 类 号：O631.5[理学—高分子化学]