液晶金属配位聚合物的合成及性能  

Synthesis and Properties of Liquid Crystalline Metallomesogenic Polymers

作　　者：黄美荣[1] 李新贵[1] 华轶敏[1] 张炜[2] 

机构地区：[1]同济大学材料学院混凝土材料国家重点实验室材料化学研究所,上海200092 [2]复旦大学聚合物分子工程教育部重点实验室高分子科学系,上海200433

出　　处：《高分子通报》2004年第1期73-80,共8页Polymer Bulletin

基　　金：国家自然科学基金 ( 2 0 2 740 3 0 ) ;复旦大学聚合物分子工程教育部重点实验室基金

摘　　要：基于国内外最新研究文献 ,系统论述了近年来液晶金属配位聚合物的合成方法、液晶行为及应用前景。指出液晶金属配位聚合物的合成方法可归纳为直接配位法、单体配位法、交联配位法和聚合物反应法四种。液晶金属配位聚合物一般呈现热致液晶行为 ,显示稳定的向列液晶相或近晶液晶相。有些金属配位聚合物还呈现互变性近晶态或单变液晶性。液晶金属配位聚合物具有金属的特殊性质 ,是一种新型高性能磁导、电导和光导材料 ,可望应用于液晶显示材料、磁性信息储存薄膜材料、润滑剂和各向异性催化剂等。A research on developments of the synthesis,liquid crystalline(LC) behavior and potential applications of several types of metallomesogenic polymers is provided based on the latest literatures.It is pointed out that four techniques such as direct coordination,monomer coordination,cross-linking coordination and polymer reaction are served for the synthesis of the metallomesogenic polymers.Metallomesongenic polymers are usually thermotropic and exhibit stable nematic or smectic LC phase.Some metallomesogenic polymers show enantiotropic smectic C and smectic A phases, and some are monotropic.Metallomesogenic polymers have special properties like metals.They are magnetically,electronically,optically conducting materials with high performance.These polymers could be potentially served as LC display materials,magnetic data-storage film materials,lubricant as well as anisotropic catalyst.

关 键 词：液晶金属配位聚合物 合成 性能 液晶行为 

分 类 号：O631[理学—高分子化学]