Pr_6O_(11)掺杂锆钛酸铅二元系压电陶瓷  

Pr_6O_(11) DOPED LEAD ZIRCONATE TITANATE BINARY SYSTEM PIEZOELECTRIC CERAMICS

作　　者：孙清池[1] 孙琳[1] 王俐聪[2] 高正虹[2] 徐廷献[1] 

机构地区：[1]天津大学材料科学与工程学院 [2]天津大学理学院,天津300072

出　　处：《硅酸盐学报》2004年第1期15-18,共4页Journal of The Chinese Ceramic Society

基　　金：天津大学先进陶瓷与加工技术教育部重点实验室资助项目。

摘　　要：固相法制备Pb0.955Pr0.03(ZryTi1-y)O3(PPZT1)和Pb1-1.5xPrx(Zr0.54Ti0.46)O3(PPZT2)系压电陶瓷,其中:x=0.02,0.04,0.06,0.08;y=0.51,0.52,0.54,0.56,0.58,0.60。XRD分析表明:PPZT1系统的准同型相界在锆的摩尔分数为55％左右。当锆的摩尔分数为54％,烧结温度为1 240℃,保温1 h,能获得优良的性能,其值分别为:d33=420×10-12C/N;ε33T/ε0=2 000;θc=314℃;Qm=76;tanδ=2％;Kp=0.53。XRD分析还表明:PPZT2系统已远离相界,组成均在四方铁电相内。尽管PPZT2系统的介电常数很高,其压电性能却低于PPZT1系统。Pb0.955Pr0.03(ZryT1-y) O3(PPZT1 )and Pb1-1.5xPrx(Zr0.54Ti0.46) O(PPZT2)piezoelectric ceramics were prepared by solid-state reaction method with the following formulas: x=0.02, 0.04, 0.06, 0.08, y=0.51, 0.52, 0.54, 0.56, 0.58, 0.60. XRD results show that the morphotropic phase boundary (MPB) of PPZT1 is located in the area where the molar fraction of Zr is near 55%. When the molar fraction of Zr is 54% and the sintering temperature is 1240°C with 1 h curing time, the excellent properties are obtained as the following: d33=420×10-12 C/N; Ε33T/Ε0=2000; θC=314°C; Qm=76; tanδ=2%; KP=0.53. XRD results also reveal that PPZT2 is far from MPB and the compositions of PPZT2 are all in tetragonal phase. So that is why PPZT2 has a lower piezoelectric property despite of a good dielectric constant compared with PPZT1.

关 键 词：锆钛酸铅陶瓷 镨掺杂 压电陶瓷 X射线衍射 

分 类 号：TM282[一般工业技术—材料科学与工程]