Synthesis and Liquid Crystal Properties of Transition Metal Complexes of Meso-tetra(4-n-myristyloxyphenyl)porphyrin  

作　　者：LIUWei SHIYu-hua SHITong-shun 

机构地区：[1]CollegeofChemistry,JilinUniversity,Changchun130023,P.R.China

出　　处：《Chemical Research in Chinese Universities》2004年第1期20-23,共4页高等学校化学研究（英文版）

基　　金：SupportedbytheNationalNaturalScienceFoundationofChina(No .5 97830 0 1)

摘　　要：Transition metal complexes of meso-tetra(4-myristyloxyphenyl)porphyrin TMPPM [M =Mn, Fe, Co, Ni, Cu, Zn; TMPP=mesotetra(4-myristyloxyphenyl)porphyrin] have been synthesized and characterized by means of elemental analyses, UV-Vis spectra, infrared photoacoustic spectra, 1H NMR spectra, molar conductance and differential scanning calorimetry(DSC). The ligand and the Zn complex show liquid crystalline behavior. According to the DSC thermogram of the Zn complex, it exhibits a lower phase transition temperature -7.453 ℃ and a wide mesophase temperature span, 77 ℃.Transition metal complexes of meso-tetra(4-myristyloxyphenyl)porphyrin TMPPM [M =Mn, Fe, Co, Ni, Cu, Zn; TMPP=mesotetra(4-myristyloxyphenyl)porphyrin] have been synthesized and characterized by means of elemental analyses, UV-Vis spectra, infrared photoacoustic spectra, 1H NMR spectra, molar conductance and differential scanning calorimetry(DSC). The ligand and the Zn complex show liquid crystalline behavior. According to the DSC thermogram of the Zn complex, it exhibits a lower phase transition temperature -7.453 ℃ and a wide mesophase temperature span, 77 ℃.

关 键 词：Transition metal complex meso-Tetra(4-n-myristyloxyphenyl)porphyrin Differential scanning calorimetry Liquid crystal 

分 类 号：O614[理学—无机化学]