1∶12系列钼钨磷混配型杂多酸(盐)的合成及性质研究  

PREPARATION AND CHARACTERIZATION OF 1∶12 SERIES OF HETEROPOLY MOLYBDOTUNGSTOPHOSPHORIC ACIDS(SALTS)

作　　者：王恩波[1] 梁虹[1] 黄如丹[1] 张淑霞[1] 

机构地区：[1]东北师范大学化学系,长春130024

出　　处：《应用化学》1992年第1期56-60,共5页Chinese Journal of Applied Chemistry

基　　金：国家自然科学基金

摘　　要：用分步法制备出高纯度、高产率的混配型钼钨磷杂多酸H_3PMo_6W_6O_(40)·xH_2O晶体,并合成出4种通式为Ln[PMo_6W_6O_(40)]·xH_2O(Ln=La,Ce,Pr,Nd)钼钨混配型稀土杂多酸盐及ZnHPMo_6W_6O_(40)·xH_2O杂多酸盐。Heteropoly molybdotungstophosphoric acids (salts) with formula Ln-PMo_6W_6O_40·xH_2O (Ln=La, Ce, Pr, Nd) and ZnHP Mo_6 W_6O_40·xH_2O were prepared and characterized by elemental analysis, IR, UV spectrometry, and x-ray diffraction.The thermal stabilities of the compounds were as follows:solid acids>rareearth salts>Zn salt.The mechanism of reduction of the heteropolyanion in aqueous solution was proposed.

关 键 词：钼钨磷多杂多酸 合成 性质 

分 类 号：O614.612[理学—无机化学]