两亲性卟啉的合成及其L-B膜  

SYNTHESES OF AMPHIPHILIC PORPHYRINS AND THEIR LANGMUIR-BLODGETT FILMS

作　　者：文珂[1] 曹锡章 

机构地区：[1]吉林大学化学系,长春130023

出　　处：《应用化学》1992年第3期70-71,共2页Chinese Journal of Applied Chemistry

摘　　要：早期L-B膜的研制主要着眼于长碳链脂肪酸及其衍生物。近来,由于对膜性能的特殊要求,人们把注意力转向丁二炔、酞菁和卟啉衍生物。本文用四一(N,N-二甲基氨基苯基)卟啉(TDMAPP)与溴代十六烷反应得到两亲性的含有4个长碳链的澳化四-(4-Tetra-(N,N-dimethylaminophenyl)porphyrin(TDMAPP) reacts with n-C_(16)H_(33)Br to give quaternary bromides of the amphiphilie porphyrin containing four long aliphatic chains. Its Cu, Zn and Co complexes have been prepared. These porphyrins are capable of forming Langmuir-Blodgett films. The UV-Visible spectra of the L-B films as well as of the solid compounds indicate that the interations between molecules in two cases are different.

关 键 词：卟啉衍生物 合成 L-B膜 

分 类 号：O626.13[理学—有机化学]