DMF和DMSO配位的金属十聚钨酸盐在非水溶剂中光致变色性质的研究  

ON PHOTOCHROMISM OF DMF AND DMSO COORDINATED METAL DECATUNGSTATES IN NON-AQUEOUS SOLVENTS

作　　者：朱思三[1] 岳斌[1] 万国江[1] 施晓群 顾翼东[1] 

机构地区：[1]复旦大学化学系,上海200433

出　　处：《应用化学》1992年第3期41-45,共5页Chinese Journal of Applied Chemistry

基　　金：国家自然科学基金

摘　　要：研究了某些DMF和DMSO配位的金属十聚钨酸盐在3种有机溶剂中的光致变色性质,通过ESR、NMR和可见吸收光谱的研究及对五价钨的测定,说明了光致变色性质的产生与金属阳离子无关,而取决于十聚钨酸根W_(10)O_(32)^(4-)、金属离子的配体及所采用溶剂。The photochromism of some DMF and DMSO coordinated metal decatungstates in DMF DMSO, and acetonitrile has been studied through ESR, ~1HNMR, risible spectra and W(Ⅴ) determination. The photochromism is found mainly to be related to the decatungstate W_(10)O_(32)^(4-), the ligands coordinated with metal ions and the solvents used.

关 键 词：配合物 十聚钨酸盐 DMSO DMF 

分 类 号：O614.613[理学—无机化学]