正交试验法研制多烷基二氢化茚  

Orthogonal Test in Preparation of Polyalkylindans

作　　者：彭军[1] 翟伦玉 于明[1] 

机构地区：[1]东北师范大学化学系,吉林长春130024

出　　处：《有机化学》1992年第1期84-87,共4页Chinese Journal of Organic Chemistry

摘　　要：近年来,双环苯型麝香化合物对香料工业具有重要意义。如粉檀麝香、吐纳麝香等。1:1,1,2,3,3, 5-Hexamethylindan is a parent constitution of polycyclic musk per-fume compounds. An orthogonal test with reaction temperature, time, amount of AlCl_3 andthe molar ratio of p-cymene to 2-methyl-2-butene as factors A, B, C, D, respectively, hasbeen conducted and it is found that the optimal condition is A_2B_3C_2D_2(0℃, 3.5h, 10% and1:1.8). The products under the optimal condition have been characterized as follows: 1,1,2,3,3, 5-hexamethylindan, 36.8% and 1,1,3, 5-tetramethy1-3-ethylindan, 11.7%(relative to p-cymene).

关 键 词：麝香香料 粉檀麝香 烷基茚满 

分 类 号：TQ655[化学工程—精细化工]