石墨炉原子吸收光谱法快速测定塑料饮水管浸出液中的痕量锑  

Rapid Determination of Trace Sb in Plastic Pipes for Dringing Water by GFAAS

作　　者：鲁丹[1] 钱燕儿[1] 

机构地区：[1]浙江省疾病预防控制中心,浙江杭州310009

出　　处：《光谱学与光谱分析》2004年第2期242-244,共3页Spectroscopy and Spectral Analysis

摘　　要：采用铜作基体改进剂、横向塞曼扣背景石墨炉原子吸收光谱法快速测定塑料饮水管浸出液中痕量锑。对石墨炉加热程序中的灰化温度和原子化温度进行了优化 ,同时也研究了介质酸度的影响。选定了最佳测量条件 ,提高了方法的灵敏度和精密度。本方法的线性范围为 0 2 7～ 2 0 0 μg·L-1 ,工作曲线回归方程为Y=0 0 0 6 8X - 0 0 0 0 2 ,相关系数r=0 9996 ,特征质量为 6 7pg ,最低检测量为 5 4pg ,回收率在 92 2 %～1 0 2 5 %。对 5 0 ,1 0 0 ,2 0 0 μg·L-1 锑的标准溶液连续测定 6次 ,相对标准偏差分别为 6 4 7% ,4 97% ,2 4 5 %。结果表明 ,该方法简便、快速、灵敏、重现性好、准确度高 。A new method for the determination of trace Sb in plastic pipes for drinking water was found. Cu is used as a matrix modifier in the transverse orientation Zeeman background dedution GFAAS to determine trace Sb in plastic pipes for drinking water rapidly. The ashing temperature and atomization temperature were obtained by optimization process. The influences of medium acidity were studied. The best measurement conditions were selected. The sensitivity and precision of the method were improved. Sb was detected directly with a linear range of 0 27 20 0 μg·L -1 . The equation of working curve is Y= 0 006 8 X-0 000 2, r=0 999 6 . The characteristic mass of the method is 6 7 pg. The detection limit is 5 4 pg. The recovery is 92 2% 102 5%. The RSDs were obtained from the data of 6 determinations at the concentration level of 5 0, 10 0 and 20 0 μg·L -1 is 6 47%, 4 97% and 2 45% respectively. The method is simple, rapid, accurate and of highly sensitive and precise. Satisfactory results are obtained.

关 键 词：石墨炉原子吸收光谱法 塑料饮水管 浸出液 锑 痕量分析 基体改进剂 铜 

分 类 号：TQ320.724[化学工程—合成树脂塑料工业] TQ320.74