一些含芳基硒、碲醌类化合物的合成  

SYNTHESIS OF SOME QUINONE-TYPE COMPOUNDS CONTAINING ARYLSELENO AND ARYLTELLURO GROUPS

作　　者：杜少斌[1] 王瑾[2] 范伟强[2] 张永敏[2] 江金龙[2] 

机构地区：[1]云南师范大学化学系 [2]杭州大学化学系

出　　处：《云南师范大学学报（自然科学版）》1992年第1期29-36,共8页Journal of Yunnan Normal University:Natural Sciences Edition

摘　　要：本文用三种不同的反应途径制备的芳基硒(碲)负离子与四氯-1,4-苯醌和2,3—二氯-1,4-茶醌反应,合成出芳基硒和碲醌类化合物,产物经质谱和^(13)C-NMR证实,此外,当2,3—二氯荼醌和α-荼基碲格氏试剂反应时,产物为2,3-α-二萘基碲荼。Arylsellenium and Aryltellurium which were obtained through three different ways reaction with tetrachloro-1,4-benzoquinone and 2,3-dichloro-1,4-naphthoquinone to gain some Novel quinone-type Compounds containing Arylselsno-and Aryltelluro-groups in high yield. Products were confirmed by MS and `(13)C-NMR. When 2,3-dichloro-1,4-naphthoquinone reacts with 1-naphthanene Grignard reagent the product is 2,3-dinaphth anenetelluro-naphthanen which is identified by MS, ~1H-NMR,`(13)C-NMR and IR.

关 键 词：醌类化合物 芳基硒 芳基碲 合成 

分 类 号：O625.46[理学—有机化学]